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Water Quality
Additives
The Art of the Water Change
What was once an esoteric luxury is now becoming a popular trend in reef husbandry.
Reef aquariums dominated by stony corals and clams deplete the supply of calcium
and bicarbonate quickly. Manual additions of additives are one option, but,
for large aquariums, it becomes very costly to sustain not to mention a bit
more work. Calcium reactors and Nilsen/Kalkwasser reactors are a very nice alternative
to manual additions of calcium and alkalinity buffer solutions. They are chemically
stable, require little maintenance, and over time can be a cost savings.
A calcium reactor consists of three main items, a chamber to hold the media,
a circulation pump, and a carbon dioxide (CO2) kit (regulator & tank). The
reactor is constantly fed CO2 to keep the water in the chamber at a lower pH.
At low pH, the media (usually aragonite) dissolves releasing calcium, bicarbonate,
and trace elements. The effluent from the reaction chamber is dripped slowly
back into the aquarium where it acts to slowly boost the calcium level in the
tank and also stabilize the pH and alkalinity. These reactors are not particularly
good at quickly raising levels of calcium or alkalinity, but rather maintaining
them once the desired level is achieved. Before running the reactor, it is a
good idea to adjust the levels of calcium and alkalinity until you are satisfied.
A Nilsen reactor is a device named after Alf Jacob Nilsen, a decorated aquarist
from Norway. It is an airtight a chamber partially filled with calcium hydroxide
powder that is constantly fed water from a reservoir. It is important that this
chamber is air tight since calcium hydroxide comes out of solution more easily
if in contact with the atmosphere. A magnetic stirrer keeps the water in the
reactor saturated by periodically stirring the powder. The kalkwasser (lime
water) requires this occasional stir because it is not particularly water-soluble
and precipitates if not regularly agitated. Unlike the calcium reactor, a Nilsen
reactor does not use the aquarium's water for the reaction. It is fed water
via a dosing pump from a container of fresh water, and saturates it with the
dissolved calcium hydroxide. That saturated effluent is then administered into
the tank as top-off water. The drawback to this method of calcium addition is
the fact that the aquarist must be evaporating enough water. If the tank evaporates
very little, then this reactor may be an ineffective method of calcium replacement.
The benefits of these two reactors are many. They are the only way I know of
constantly maintain high levels of calcium and alkalinity while getting the
added benefit of trace element additions. The real beauty of a reactor is that
it doses everything slowly. When you add supplements or do water changes, there
is a chance of shocking your inhabitants, or worse yet, wounding them irreparably
by improperly dosing an additive. On larger aquariums, they are more cost effective
over time than using conventional additives. Many aquarists have chosen to spend
the money up front and enjoy the peace of mind these reactors provide.
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